R-phrases | |
R1 | Explosive when dry. |
R2 | Risk of explosion by shock, friction, fire or other sources of ignition. |
R3 | Extreme risk of explosion by shock, friction, fire or other sources of ignition. |
R4 | Forms very sensitive explosive metallic compounds. |
R5 | Heating may cause an explosion. |
R6 | Explosive with or without contact with air. |
R7 | May cause fire. |
R8 | Contact with combustible material may cause fire. |
R9 | Explosive when mixed with combustible material. |
R10 | Flammable. |
R11 | Highly Flammable. |
R12 | Extremely flammable. |
R13 | (Obsolete) Extremely flammable liquid gas. (This R-phrase is no longer included in Regulation.) |
R14 | Reacts violently with water. |
R15 | Contact with water liberates extremely flammable gases. |
R16 | Explosive when mixed with oxidizing substances. |
R17 | Spontaneously flammable in air. |
R18 | In use, may form flammable/explosive vapour-air mixture. |
R19 | May form explosive peroxides. |
R20 | Harmful by inhalation. |
R21 | Harmful in contact with skin. |
R22 | Harmful if swallowed. |
R23 | Toxic by inhalation. |
R24 | Toxic in contact with skin. |
R25 | Toxic if swallowed. |
R26 | Very toxic by inhalation. |
R27 | Very toxic in contact with skin. |
R28 | Very toxic if swallowed. |
R29 | Contact with water liberates toxic gas. |
R30 | Can become highly flammable in use. |
R31 | Contact with acids liberates toxic gas. |
R32 | Contact with acids liberates very toxic gas. |
R33 | Danger of cumulative effects. |
R34 | Causes burns. |
R35 | Causes severe burns. |
R36 | Irritating to eyes. |
R37 | Irritating to respiratory system. |
R38 | Irritating to skin. |
R39 | Danger of very serious irreversible effects. |
R40 | Limited evidence of a carcinogenic effect. |
R41 | Risk of serious damage to eyes. |
R42 | May cause sensitization by inhalation. |
R43 | May cause sensitization by skin contact. |
R44 | Risk of explosion if heated under confinement. |
R45 | May cause cancer. |
R46 | May cause heritable genetic damage. |
R47 | (Obsolete) May cause deformities. (This R-phrase is no longer included in Regulation.) |
R48 | Danger of serious damage to health by prolonged exposure. |
R49 | May cause cancer by inhalation. |
R50 | Very toxic to aquatic organisms. |
R51 | Toxic to aquatic organisms. |
R52 | Harmful to aquatic organisms. |
R53 | May cause long-term adverse effects in the aquatic environment. |
R54 | Toxic to flora. |
R55 | Toxic to fauna. |
R56 | Toxic to soil organisms. |
R57 | Toxic to bees. |
R58 | May cause long-term adverse effects in the environment. |
R59 | Dangerous for the ozone layer. |
R60 | May impair fertility. |
R61 | May cause harm to the unborn child. |
R62 | Possible risk of impaired fertility. |
R63 | Possible risk of harm to the unborn child. |
R64 | May cause harm to breastfed babies. |
R65 | Harmful: may cause lung damage if swallowed. |
R66 | Repeated exposure may cause skin dryness or cracking. |
R67 | Vapours may cause drowsiness and dizziness. |
R68 | Possible risks of irreversible effects. |
Combinations of R phrases | |
R14/15 | Reacts violently with water, liberating extremely flammable gases. |
R15/29 | Contact with water liberates toxic, extremely flammable gas. |
R20/21 | Harmful by inhalation and in contact with skin. |
R20/21/22 | Harmful by inhalation, in contact with skin and if swallowed. |
R20/22 | Harmful by inhalation and if swallowed. |
R21/22 | Harmful in contact with skin and if swallowed. |
R23/24 | Toxic by inhalation and in contact with skin. |
R23/24/25 | Toxic by inhalation, in contact with skin and if swallowed. |
R23/25 | Toxic by inhalation and if swallowed. |
R24/25 | Toxic in contact with skin and if swallowed. |
R26/27 | Very toxic by inhalation and in contact with skin. |
R26/27/28 | Very toxic by inhalation, in contact with skin and if swallowed. |
R26/28 | Very toxic by inhalation and if swallowed. |
R27/28 | Very toxic in contact with skin and if swallowed. |
R36/37 | Irritating to eyes and respiratory system. |
R36/37/38 | Irritating to eyes, respiratory system and skin. |
R36/38 | Irritating to eyes and skin. |
R37/38 | Irritating to respiratory system and skin. |
R39/23 | Toxic: danger of very serious irreversible effects through inhalation. |
R39/23/24 | Toxic: danger of very serious irreversible effects through inhalation and in contact with skin. |
R39/23/24/25 | Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. |
R39/23/25 | Toxic: danger of very serious irreversible effects through inhalation and if swallowed. |
R39/24 | Toxic: danger of very serious irreversible effects in contact with skin. |
R39/24/25 | Toxic: danger of very serious irreversible effects in contact with skin and if swallowed. |
R39/25 | Toxic: danger of very serious irreversible effects if swallowed. |
R39/26 | Very toxic: danger of very serious irreversible effects through inhalation. |
R39/26/27 | Very toxic: danger of very serious irreversible effects through inhalation and in contact with skin. |
R39/26/27/28 | Very toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. |
R39/26/28 | Very toxic: danger of very serious irreversible effects through inhalation and if swallowed. |
R39/27 | Very toxic: danger of very serious irreversible effects in contact with skin. |
R39/27/28 | Very toxic: danger of very serious irreversible effects in contact with skin and if swallowed. |
R39/28 | Very toxic: danger of very serious irreversible effects if swallowed. |
R42/43 | May cause sensitization by inhalation and skin contact. |
R48/20 | Harmful: danger of serious damage to health by prolonged exposure through inhalation. |
R48/20/21 | Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. |
R48/20/21/22 | Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. |
R48/20/22 | Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. |
R48/21 | Harmful: danger of serious damage to health by prolonged exposure in contact with skin. |
R48/21/22 | Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. |
R48/22 | Harmful: danger of serious damage to health by prolonged exposure if swallowed. |
R48/23 | Toxic: danger of serious damage to health by prolonged exposure through inhalation. |
R48/23/24 | Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. |
R48/23/24/25 | Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. |
R48/23/25 | Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. |
R48/24 | Toxic: danger of serious damage to health by prolonged exposure in contact with skin. |
R48/24/25 | Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. |
R48/25 | Toxic: danger of serious damage to health by prolonged exposure if swallowed. |
R50/53 | Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
R51/53 | Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
R52/53 | Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
R68/20 | Harmful: possible risk of irreversible effects through inhalation. |
R68/20/21 | Harmful: possible risk of irreversible effects through inhalation and in contact with skin. |
R68/20/21/22 | Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. |
R68/20/22 | Harmful: possible risk of irreversible effects through inhalation and if swallowed. |
R68/21 | Harmful: possible risk of irreversible effects in contact with skin. |
R68/21/22 | Harmful: possible risk of irreversible effects in contact with skin and if swallowed. |
R68/22 | Harmful: possible risk of irreversible effects if swallowed. |
S-phrases | |
S1 | Keep locked up. |
S2 | Keep out of the reach of children. |
S3 | Keep in a cool place. |
S4 | Keep away from living quarters. |
S5 | Keep contents under ... (appropriate liquid to be specified by the manufacturer). |
S6 | Keep contents under ... (appropriate gas to be specified by the manufacturer). |
S7 | Keep container tightly closed. |
S8 | Keep container dry. |
S9 | Keep container in a well-ventilated place. |
S10 | (Obsolete) Keep content wet. (This S phrase is no longer included in Regulation.) |
S11 | (Obsolete) Avoid contact with air. (This S phrase is no longer included in Regulation.) |
S12 | Do not keep the container sealed. |
S13 | Keep away from food, drink and animal feedingstuffs. |
S14 | Keep away from ... (incompatible materials to be indicated by the manufacturer). |
S15 | Keep away from heat. |
S16 | Keep away from sources of ignition - No smoking. |
S17 | Keep away from combustible material. |
S18 | Handle and open container with care. |
S20 | When using do not eat or drink. |
S21 | When using do not smoke. |
S22 | Do not breathe dust. |
S23 | Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). |
S24 | Avoid contact with skin. |
S25 | Avoid contact with eyes. |
S26 | In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
S27 | Take off immediately all contaminated clothing. |
S28 | After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). |
S29 | Do not empty into drains. |
S30 | Never add water to this product. |
S31 | (Obsolete) Keep away from explosive materials. (This S phrase is no longer included in Regulation.) |
S33 | Take precautionary measures against static discharges. |
S34 | (Obsolete) Avoid strokes and frictions. (This S phrase is no longer included in Regulation.) |
S35 | This material and its container must be disposed of in a safe way. |
S36 | Wear suitable protective clothing. |
S37 | Wear suitable gloves. |
S38 | In case of insufficient ventilation, wear suitable respiratory equipment. |
S39 | Wear eye/face protection. |
S40 | To clean the floor and all objects contaminated by this material, use ... (to be specified by the manufacturer). |
S41 | In case of fire and/or explosion do not breathe fumes. |
S42 | During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer). |
S43 | In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases risk, add - 'Never use water') |
S44 | (Obsolete) If you feel unwell, seek medical advice immediately. (Show the label where possible.) (This S phrase is no longer included in Regulation.) |
S45 | In case of accident or if you feel unwell, seek medical advice immediately. (Show the label where possible.) |
S46 | If swallowed, seek medical advice immediately and show this container or label. |
S47 | Keep at temperature not exceeding ... °C. (To be specified by the manufacturer). |
S48 | Keep wet with ... (appropriate material to be specified by the manufacturer). |
S49 | Keep only in the original container. |
S50 | Do not mix with ... (to be specified by the manufacturer). |
S51 | Use only in well-ventilated areas. |
S52 | Not recommended for interior use on large surface areas. |
S53 | Avoid exposure - obtain special instructions before use. |
S54 | (Obsolete) Before draining of to sewage disposal plant ask for permission of the competent authority. (This S phrase is no longer included in Regulation.) |
S55 | (Obsolete) Before draining of into the sewage system or into waters treat according to state of art. (This S phrase is no longer included in Regulation.) |
S56 | Dispose of this material and its container at hazardous or special waste collection point. |
S57 | Use appropriate container to avoid environmental contamination. |
S58 | (Obsolete) Dispose as hazardous waste. (This S phrase is no longer included in Regulation.) |
S59 | Refer to manufacturer/supplier for information on recovery/recycling. |
S60 | This material and its container must be disposed of as hazardous waste. |
S61 | Avoid release to the environment. Refer to special instructions / Safety data sheets. |
S62 | If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. |
S63 | In case of accident by inhalation: remove casualty to fresh air and keep at rest. |
S64 | If swallowed, rinse mouth with water (only if the person is conscious). |
Combinations of S phrases | |
S1/2 | Keep locked up and out of the reach of children. |
S3/7 | Keep container tightly closed in a cool place. |
S3/7/9 | (obsolete) Keep container tightly closed in a cool, well-ventilated place. |
S3/9 | (obsolete) Keep container in a cool, well-ventilated place. |
S3/9/14 | Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer). |
S3/9/14/49 | Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer). |
S3/9/49 | Keep only in the original container in a cool well-ventilated place. |
S3/14 | Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer). |
S7/8 | Keep container tightly closed and dry. |
S7/9 | Keep container tightly closed and in a well-ventilated place. |
S7/47 | Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by the manufacturer). |
S20/21 | When using do not eat, drink or smoke. |
S24/25 | Avoid contact with skin and eyes. |
S27/28 | Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). |
S29/35 | Do not empty into drains. This material and its container must be disposed of in a safe way. |
S29/56 | Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. |
S36/37 | Wear suitable protective clothing and gloves. |
S36/37/39 | Wear suitable protective clothing, gloves and eye/face protection. |
S36/39 | Wear suitable protective clothing and eye/face protection. |
S37/39 | Wear suitable gloves and eye/face protection. |
S47/49 | Keep only in the original container at a temperature not exceeding ... °C (to be specified by the manufacturer). |